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Mining & Production · Rutile · 5 min read

Waves and wind did the first round of mineral sorting

Rivers carry weathered minerals to the coast, where waves, tides and wind sort them by size and density and leave several valuable minerals mixed together in one sand.

Reviewed by Peter Uppal

Low view of a dune crest, a veil of pale sand streaming off it in the wind, ribbons of mixed dark grains lying on the slope below.
Illustrative artwork: wind lifting pale sand off a dune crest and leaving darker grains behind. Not a facility, equipment or material connected to this project. · Illustration · Osmond Hub

The short version

The USGS deposit model says coastal heavy-mineral sands are formed by the physical-mechanical concentration of bedrock minerals freed by weathering(opens in a new tab). The same model describes waves, tides, longshore currents and wind as effective mechanisms for sorting the mineral grains on the basis of differences in their size and density(opens in a new tab). On this publication's reading, a sorting process that responds to size and density gathers several chemically different minerals into one sand, and taking that mixture apart again is the processing plant's job.

A long way from the source rock

The process begins inland, where high-grade metamorphic and igneous rocks that contain heavy minerals weather and erode(opens in a new tab). In its general description the USGS model widens the list of contributors to igneous, metamorphic, and sedimentary rocks(opens in a new tab). The broken-down material then travels: streams and rivers carry the detritus to the coast(opens in a new tab).

Geoscience Australia describes the same process. In its account, over millions of years the source rocks were weathered and eroded(opens in a new tab), and the harder minerals including quartz were washed down to the sea by heavy rainfall and fast flowing streams(opens in a new tab).

Which minerals arrive intact depends on how durable they are. The USGS model states that the economic heavy minerals in coastal deposits are particularly durable and resistant to chemical breakdown, and thus they survive the turbulent journey from the bedrock source area to the coast(opens in a new tab). Geoscience Australia describes rutile, ilmenite, zircon, garnet, magnetite, diamond and monazite as hard minerals that are resistant to weathering(opens in a new tab).

Geoscience Australia's own sentence has quartz arriving at the sea alongside them. What parts the two groups at the coast is a difference in size and density(opens in a new tab).

How heavy is heavy

The USGS model gives the working line: heavy minerals are generally defined as dense minerals that have a specific gravity greater than 2.85(opens in a new tab). The USGS glossary adds, for comparison, that quartz has a specific gravity of approximately 2.65(opens in a new tab). Differences in density of that kind, along with grain size, are what the shoreline works on.

The beach as the first separator

The USGS model says the mechanisms that do the sorting are interpreted to be surf wave action in the swash zone of a beach, high energy surf and surge driven by turbulence during storm events, and long-shore drift(opens in a new tab). Between them, the forces of waves, tides, and longshore drift work the detritus, selectively carrying off lighter grains and leaving a fine-grained accumulation of heavy, dense mineral grains(opens in a new tab).

Most of this happens in one zone. Mineral sorting occurs mainly on the upper part of the high-tide swash zone(opens in a new tab). USGS describes the principal zone of separation as the upper part of the beach face, also known as the swash zone (the foreshore)(opens in a new tab). There, variations in particle settling velocities due to differences in mineral densities work in concert with wave and tide actions in the swash zone to effectively segregate heavies from lights(opens in a new tab). Victoria's fact sheet describes the outgoing half of each wave doing the removal: backwash carries lighter minerals such as quartz back into the sea(opens in a new tab).

The USGS model quotes a 1991 study by Force describing heavy-mineral concentration as "a process involving lag enrichment on the swash face"(opens in a new tab), meaning that the heavy grains are what is left behind, in a process in which erosion dominates deposition(opens in a new tab). Not all of them are sorted equally well: the finest-grained, most dense heavy minerals are the most effectively sorted(opens in a new tab).

Wind takes a second pass. According to USGS, wind can be a very effective mechanism for sorting the heavy, dense minerals from the lighter grains of sand(opens in a new tab), and "fine-grained sands and heavy minerals on the foreshore can be remobilized by winds, forming heavy mineral-rich sand dunes behind the beach"(opens in a new tab). Victoria's fact sheet says that onshore winds that blow lighter grains inland can also concentrate heavier minerals at the front of coastal dunes(opens in a new tab).

Repeated over time, these sorting processes can form discrete thin layers and composite intervals in the sediments composed of dominantly heavy minerals(opens in a new tab). USGS reports that most economic deposits of heavy-mineral sands are Paleogene, Neogene, and Quaternary in age; some are modern coastal deposits(opens in a new tab), and that heavy-mineral sands operations exploit deposits that range in age from Cretaceous to Holocene(opens in a new tab).

"Backwash efficiently sorts the available material, to produce a layer enriched in fine dense minerals." Force (1991), as quoted by USGS

Why the result is a mixture

What the beach leaves is a suite of minerals. USGS reports that the suite of heavy minerals most commonly includes ilmenite, rutile, leucoxene (altered ilmenite) and zircon, and can also contain sillimanite/kyanite, staurolite, monazite and garnet(opens in a new tab). It adds that in the vast majority of heavy-mineral sands, ilmenite is the most abundant heavy mineral and the principal ore mineral(opens in a new tab), and that together, ilmenite, rutile, and zircon often compose more than 80 percent of the heavy mineral suite(opens in a new tab). Geoscience Australia names rutile, ilmenite, zircon and monazite as the important minerals in mineral sands, with garnet, magnetite, sapphire, diamond and staurolite also mined from some deposits(opens in a new tab).

These minerals carry different elements. USGS groups ilmenite, rutile and leucoxene as titanium-bearing minerals(opens in a new tab), while monazite is a source of rare earth elements as well as thorium(opens in a new tab).

The mixture can also change after it is laid down. USGS notes that heavy mineral grains appear to weather primarily after their deposition in the coastal plain(opens in a new tab), and that iron is leached from ilmenite during weathering, which thereby upgrades the titanium dioxide (TiO₂) content of the ilmenite, forming leucoxene(opens in a new tab).

On this publication's reading, a sorting process that selects for density and size does not sort by chemistry, so titanium, zirconium and rare-earth minerals arrive together.

What the plant has to undo

In the IAEA's outline of the zircon supply chain, heavy-mineral sands are processed by gravity separation to produce a concentrate containing more than 95% heavy minerals(opens in a new tab). Zircon and other minerals of value, such as ilmenite, rutile and monazite, are then separated from the complex mineral mix by magnetic and electrostatic separation processes(opens in a new tab).

Kenmare Resources describes a version of this sequence at its Moma mine. There, Kenmare says, the ore feed passes over "progressive stages of gravity spirals"(opens in a new tab), which separate a heavy mineral concentrate from tailings of silica sand and clay. Kenmare states that its mineral separation plant then uses magnetic, gravity and electrostatic circuits to separate ilmenite, rutile, zircon and monazite into individual products(opens in a new tab).

For the later stages, both descriptions name magnetic and electrostatic separation, and Kenmare's plant also uses gravity circuits(opens in a new tab).

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